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Identification of an X-Band Clock Transition in Cp'Pr Enabled by a 4f5d Configuration.
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J Am Chem Soc
38387072
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15 |
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Synthesis of Crystallographically Characterizable Bis(cyclopentadienyl) Sc(II) Complexes: (CHBu)Sc and {[CH(SiMe)]ScI}.
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38264991
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15 |
2024 |
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Perplexing EPR Signals from 5f6d U(II) Complexes.
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38279200
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4.6 |
2024 |
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Investigating Steric and Electronic Effects in the Synthesis of Square Planar 6d Th(III) Complexes.
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Inorg Chem
38502000
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0 |
4.6 |
2024 |
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Synthesis and Crystallographic Characterization of a Reduced Bimetallic Yttrium -Metallocene Hydride Complex, [K(crypt)][(μ-Cp)Y(μ-H)] (Cp = MeSi[CH(SiMe)-3]), with a 3.4 Å Yttrium-Yttrium Distance.
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J Am Chem Soc
37133919
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15 |
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Correction to "Synthesis and Crystallographic Characterization of a Reduced Bimetallic Yttrium -Metallocene Hydride Complex, [K(crypt)][(μ-Cp)Y(μ-H)] (Cp = MeSi[CH(SiMe)-3]), with a 3.4 Å Yttrium-Yttrium Distance".
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J Am Chem Soc
37339481
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Reductive C-O Cleavage of Ethereal Solvents and 18-Crown-6 in Ln(NR)/KC Reactions (R = SiMe).
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Inorg Chem
36988455
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Room-Temperature Stable Ln(II) Complexes Supported by 2,6-Diadamantyl Aryloxide Ligands.
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36595714
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4.6 |
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Stabilization of Pu(IV) in PuBr(OPCy) and Comparisons with Structurally Similar ThX(OPR) (R = Cy, Ph) Molecules.
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Inorg Chem
37875401
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4.6 |
2023 |
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Trimethyltriazacyclohexane coordination chemistry of simple rare-earth metal salts.
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36938859
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4 |
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A MHz X-ray diffraction set-up for dynamic compression experiments in the diamond anvil cell.
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37318367
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2.5 |
2023 |
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Graphite resistive heated diamond anvil cell for simultaneous high-pressure and high-temperature diffraction experiments.
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Rev Sci Instrum
37540120
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1.6 |
2023 |
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A 9.2-GHz clock transition in a Lu(II) molecular spin qubit arising from a 3,467-MHz hyperfine interaction.
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Nat Chem
35288686
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11 |
21.8 |
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Solid-State End-On to Side-On Isomerization of (N═N) in {[(RN)Nd]N} (R = SiMe) Connects In Situ Ln(NR)/K and Isolated [Ln(NR)] Dinitrogen Reduction.
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36074041
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15 |
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2.2.2-Cryptand complexes of neptunium(III) and plutonium(III).
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4.9 |
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Anion-induced disproportionation of Th(III) complexes to form Th(II) and Th(IV) products.
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35403646
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4.9 |
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Synthesis of Trimethyltriazacyclohexane (Metach) Sandwich Complexes of Uranium, Neptunium, and Plutonium Triiodides: (Metach)AnI.
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Inorg Chem
36576312
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4.6 |
2022 |
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Reduction of Rare-Earth Metal Complexes Induced by γ Irradiation.
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Inorg Chem
36282945
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4.6 |
2022 |
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Expanding Bismuth Trihalide Coordination Chemistry with Trimethyltriazacyclohexane and Trimethyltriazacyclononane.
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Inorg Chem
35861795
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4.6 |
2022 |
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Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes.
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Inorg Chem
35504019
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2 |
4.6 |
2022 |
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Identification of the U(V) complex (CMe)UI(NSiMe) in the reaction of (CMe)UI(THF) with NSiMe.
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Dalton Trans
35980149
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4 |
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Simultaneous imaging and diffraction in the dynamic diamond anvil cell.
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35649806
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Identifying Patients with Bicuspid Aortic Valve Disease in UK Primary Care: A Case-Control Study and Prediction Model.
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36013239
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The perceptions of cancer health-care practitioners in New Zealand and the USA toward psychedelic-assisted therapy with cancer patients: A cross-sectional survey.
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Isolation and characterization of a californium metallocene.
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Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS-Bridged Dilanthanide Complexes.
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34029482
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2 |
16.383 |
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High-Resolution X-ray Photoelectron Spectroscopy of Organometallic (CHSiMe)Ln and [(CHSiMe)Ln] Complexes (Ln = Sm, Eu, Gd, Tb).
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J Am Chem Soc
34586787
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2 |
16.383 |
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A Rare-Earth Metal Retrospective to Stimulate All Fields.
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34677044
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4 |
16.383 |
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Electrochemical studies of tris(cyclopentadienyl)thorium and uranium complexes in the +2, +3, and +4 oxidation states.
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9.969 |
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X-ray Free Electron Laser-Induced Synthesis of ε-Iron Nitride at High Pressures.
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6.888 |
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Reductive Reactivity of the 4f5d Gd(II) Ion in {Gd[N(SiMe)]}: Structural Characterization of Products of Coupling, Bond Cleavage, Insertion, and Radical Reactions.
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34606242
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Density Functional Theory Analysis of the Importance of Coordination Geometry for 5f6d versus 5f Electron Configurations in U(II) Complexes.
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34644069
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5.436 |
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Compression-rate dependence of pressure-induced phase transitions in Bi.
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Cancer Healthcare Workers' Perceptions toward Psychedelic-Assisted Therapy: A Preliminary Investigation.
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Cooperative dinitrogen capture by a diboraanthracene/samarocene pair.
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34693957
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4.569 |
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Evaluating electrochemical accessibility of 4f5d and 4f Ln(II) ions in (CHSiMe)Ln and (CMeH)Ln complexes.
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Dalton Trans
34569559
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2 |
4.569 |
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Novel experimental setup for megahertz X-ray diffraction in a diamond anvil cell at the High Energy Density (HED) instrument of the European X-ray Free-Electron Laser (EuXFEL).
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33949979
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Crystallographic characterization of (CHSiMe)U(BH).
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Crystallographic characterization of rare-earth cyano-tri-phenyl-borate complexes and the cyano-borates [NCBPh], [NCBPhMe], and [NCBPh(μ-O)BPh].
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Formation of the End-on Bound Lanthanide Dinitrogen Complexes [(RN)Ln-N═N-Ln(NR)] from Divalent [(RN)Ln] Salts (R = SiMe).
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Synthesis of Ln -in-Cryptand Complexes by Chemical Reduction of Ln -in-Cryptand Precursors: Isolation of a Nd -in-Cryptand Complex.
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15.336 |
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The importance of the counter-cation in reductive rare-earth metal chemistry: 18-crown-6 instead of 2,2,2-cryptand allows isolation of [Y(NR)] and ynediolate and enediolate complexes from CO reactions.
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34123296
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Evaluating Electron-Transfer Reactivity of Complexes of Actinides in +2 and +3 Oxidation States by using EPR Spectroscopy.
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31830384
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A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes.
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Stabilization of U(III) to Oxidation and Hydrolysis by Encapsulation Using 2.2.2-Cryptand.
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33226794
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5.165 |
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A Single Small-Scale Plutonium Redox Reaction System Yields Three Crystallographically-Characterizable Organoplutonium Complexes.
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A 12-month continuous and intermittent high-impact exercise intervention and its effects on bone mineral density in early postmenopausal women: a feasibility randomized controlled trial.
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Crystal structure of the [(THF)Cs(μ-η:η-Cp')Yb] oligomer.
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Synthesis and crystallographic characterization of di-phenyl-amide rare-earth metal complexes (NPh)(THF) and [(PhN) (μ-NPh)].
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Reductive cleavage of ,'-di--butyl-carbodi-imide generates -butyl-cyanamide ligands, (MeCNCN), that bind potassium both end-on and side-on in the same single crystal.
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Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OCHBu-2,6-Me-4)].
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[Am(C Me H) ]: An Organometallic Americium Complex.
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Engineering electronic structure to prolong relaxation times in molecular qubits by minimising orbital angular momentum.
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Isolation of U(ii) compounds using strong donor ligands, CMeH and N(SiMe), including a three-coordinate U(ii) complex.
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Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI(THF) Precursors (Ln = Sm, Eu, Yb).
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In search of tris(trimethylsilylcyclopentadienyl) thorium.
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Sexual dimorphism explains residual variance around the survival-reproduction tradeoff in lizards: Implications for sexual conflict over life-history evolution.
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Two-phase equation of state for lithium fluoride.
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2.991 |
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Synthesis and Reduction of Bimetallic Methyl-Bridged Rare-Earth Metal Complexes, [(CHSiMe)Ln(μ-CH)] (Ln = Y, Tb, Dy).
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ACS Omega
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2.87 |
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New dynamic diamond anvil cells for tera-pascal per second fast compression x-ray diffraction experiments.
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5 |
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Identification of the Formal +2 Oxidation State of Neptunium: Synthesis and Structural Characterization of {Np[CH(SiMe)]}.
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Electrocatalytic HO Reduction with f-Elements: Mechanistic Insight and Overpotential Tuning in a Series of Lanthanide Complexes.
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29378127
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Single crystal toroidal diamond anvils for high pressure experiments beyond 5 megabar.
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Synthesis of uranium-in-cryptand complexes.
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Rare-Earth Metal(II) Aryloxides: Structure, Synthesis, and EPR Spectroscopy of [K(2.2.2-cryptand)][Sc(OC H tBu -2,6-Me-4) ].
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Chemistry
30199585
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Synthesis, Structure, and Magnetism of Tris(amide) [Ln{N(SiMe ) } ] Complexes of the Non-traditional +2 Lanthanide Ions.
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Chemistry
29490123
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8 |
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Using Diamagnetic Yttrium and Lanthanum Complexes to Explore Ligand Reduction and C-H Bond Activation in a Tris(aryloxide)mesitylene Ligand System.
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Inorg Chem
30246533
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Utility of Lithium in Rare-Earth Metal Reduction Reactions to Form Nontraditional Ln Complexes and Unusual [Li(2.2.2-cryptand)] Cations.
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Metal versus Ligand Reduction in Ln Complexes of a Mesitylene-Anchored Tris(Aryloxide) Ligand.
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29457716
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4.85 |
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Chelate-Free Synthesis of the U(II) Complex, [(CH(SiMe))U], Using Li and Cs Reductants and Comparative Studies of La(II) and Ce(II) Analogs.
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Inorg Chem
30182717
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Isolation of reactive Ln(ii) complexes with CHMe ligands (Cp) using inverse sandwich countercations: synthesis and structure of [(18-crown-6)K(μ-Cp)K(18-crown-6)][CpLn] (Ln = Tb, Ho).
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NH and (NH) as ligands in yttrium metallocene chemistry.
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29561007
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A simple and portable multi-channel pyrometer allowing temperature measurements down to 800 K on the microsecond scale.
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Identification of the Formal +2 Oxidation State of Plutonium: Synthesis and Characterization of {Pu[CH(SiMe)]}.
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Covalency in Americium(III) Hexachloride.
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Synthesis, Structure, and Reactivity of the Sterically Crowded Th Complex (CMe)Th Including Formation of the Thorium Carbonyl, [(CMe)Th(CO)][BPh].
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28240899
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End-On Bridging Dinitrogen Complex of Scandium.
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Anomalous elastic properties across the γ to α volume collapse in cerium.
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Giant coercivity and high magnetic blocking temperatures for N radical-bridged dilanthanide complexes upon ligand dissociation.
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Solution Synthesis, Structure, and CO Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe ) ] }.
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13 |
12.102 |
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Comparisons of lanthanide/actinide +2 ions in a tris(aryloxide)arene coordination environment.
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Evaluating the electronic structure of formal Ln ions in Ln(CHSiMe) using XANES spectroscopy and DFT calculations.
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9.063 |
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Synthesis of rare-earth-metal-in-cryptand dications, [Ln(2.2.2-cryptand)], from Sm, Eu, and Yb silyl metallocenes (CHSiMe)Ln(THF).
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Small-Scale Metal-Based Syntheses of Lanthanide Iodide, Amide, and Cyclopentadienyl Complexes as Analogues for Transuranic Reactions.
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Slow Magnetic Relaxation in a Dysprosium Ammonia Metallocene Complex.
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29166013
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Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).
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28459590
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Expanding Thorium Hydride Chemistry Through Th²⁺, Including the Synthesis of a Mixed-Valent Th⁴⁺/Th³⁺ Hydride Complex.
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Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb).
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Raman spectroscopy of the N-N bond in rare earth dinitrogen complexes.
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Record High Single-Ion Magnetic Moments Through 4f(n)5d(1) Electron Configurations in the Divalent Lanthanide Complexes [(C5H4SiMe3)3Ln]⁻.
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Synthesis, Structure, and Reactivity of the Ethyl Yttrium Metallocene, (C5Me5)2Y(CH2CH3), Including Activation of Methane.
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Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La and Ce are four electron reductants.
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Expanding the Chemistry of Molecular U(2+) Complexes: Synthesis, Characterization, and Reactivity of the {[C5 H3 (SiMe3 )2 ]3 U}(-) Anion.
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Magnetic susceptibility of uranium complexes.
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Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures.
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Structural, spectroscopic, and theoretical comparison of traditional vs recently discovered Ln(2+) ions in the [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln] complexes: the variable nature of Dy(2+) and Nd(2+).
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Synthesis of air-stable, volatile uranium(IV) and (VI) compounds and their gas-phase conversion to uranium oxide films.
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Synthesis, structure, and reactivity of crystalline molecular complexes of the {[CH(SiMe)]Th} anion containing thorium in the formal +2 oxidation state.
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A half-sandwich organometallic single-ion magnet with hexamethylbenzene coordinated to the Dy(III) ion.
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Nitric oxide insertion reactivity with the bismuth-carbon bond: formation of the oximate anion, [ON=(C6H2tBu2O)]-, from the oxyaryl dianion, (C6H2tBu2O)2-.
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Evidence-based evaluation of potential benefits and safety of beta-alanine supplementation for military personnel.
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Reactivity of organothorium complexes with TEMPO.
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Cocrystallization of (μ-S2)2- and (μ-S)2- and formation of an [η2-S3N(SiMe3)2] ligand from chalcogen reduction by (N2)2- in a bimetallic yttrium amide complex.
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Structural complexity in the rare earth metallocene hydride complexes, [(C₅Me₅)₂LnH]₂.
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Bismuth-based cyclic synthesis of 3,5-di-tert-butyl-4-hydroxybenzoic acid via the oxyarylcarboxy dianion, (O2CC6H2(t)Bu2O)2-.
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Thermal resistance at an interface between a crystal and its melt.
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Electronic structures of organometallic complexes of f elements LXXXIII: First comparison of experimental and calculated (on the basis of density functional theory) polarized Raman spectra of an oriented organometallic single crystal: Tris(pentamethylcyclopentadienyl)lanthanum.
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Insertion of CO2 and COS into Bi-C bonds: reactivity of a bismuth NCN pincer complex of an oxyaryl dianionic ligand, [2,6-(Me2NCH2)2C6H3]Bi(C6H2(t)Bu2O).
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Identification of the +2 oxidation state for uranium in a crystalline molecular complex, [K(2.2.2-cryptand)][(C5H4SiMe3)3U].
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Completing the series of +2 ions for the lanthanide elements: synthesis of molecular complexes of Pr2+, Gd2+, Tb2+, and Lu2+.
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Dinitrogen reduction via photochemical activation of heteroleptic tris(cyclopentadienyl) rare-earth complexes.
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Longitudinal changes in total body creatine pool size and skeletal muscle mass using the D-creatine dilution method.
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Bed rest worsens impairments in fat and glucose metabolism in older, overweight adults.
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Mechano-growth factor peptide, the COOH terminus of unprocessed insulin-like growth factor 1, has no apparent effect on myoblasts or primary muscle stem cells.
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Longitudinal changes in high-density lipoprotein cholesterol and cardiovascular events in older adults.
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Strength and Debye temperature measurements of cerium across the γ → α volume collapse: the lattice contribution.
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Age attenuates leucine oxidation after eccentric exercise.
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High-temperature experiments using a resistively heated high-pressure membrane diamond anvil cell.
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